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122 Publikationen filtern

Die Publikationen filtern

Hervorgehobene Autoren sind Angehörige der Universität Jena.

  1. Unraveling processes in an alkaline water electrolysis cell with reference electrodes and electrochemical impedance spectroscopy

    ErscheinungsjahrErschienen in:International journal of hydrogen energy : official journal of the International Association for Hydrogen Energy J. Scholl, C. Plank, J. Odrobina, M. Danzer, K. Skadell, M. Stelter
    A zero-gap full cell for alkaline water electrolysis is equipped with two reference electrodes. The anode (NiO mesh), the cathode (Ni mesh), and the diaphragm are investigated simultaneously by analyzing the polarization curves and utilizing electrochemical impedance spectroscopy (EIS) and distribution of relaxation times (DRT) analysis. The shares of cell voltage are 44 % of the cathode, 23 % of the anode and 33 % of the diaphragm at 0.4 A/cm². EIS and DRT analysis focus particularly on the diaphragm, revealing a complex behavior that cannot be described merely as an ohmic resistor as it is traditionally done. EIS shows that the total resistance of the diaphragm comprises an ohmic contribution and a polarization behavior. This behavior is attributed to a funnel effect of OH− ions through the diaphragm. The effect results in a change in the concentration profile near the diaphragm, leading to concentration polarization. To gain deeper insights, two equivalent circuit models with a focus on the diaphragm are developed to describe the behavior of the full cell. Both models showed that the diaphragm cannot be described by a simple ohmic resistance, and the resistance estimated by analyzing the polarization curve is a sum of multiple resistances.
    Universitätsbibliographie Jena:
    fsu_mods_00029585Externer Link

  2. The Harmful Footprint of Aged Biomicroplastics on Algal Development: A Comparative Study of Polylactic Acid, Polyhydroxybutyrate, and Cellulose Acetate

    ErscheinungsjahrErschienen in:ACS Omega P. Walz, S. Redlich, M. Hermesdorf, L. Calderón-Rodríguez, M. Franke, D. Leistenschneider, Q. Roode-Gutzmer, F. Schacher, M. Stelter, T. Wichard, P. Braeutigam
    Biopolymers are increasingly produced as sustainable alternatives to plastics, but their degradation in aquatic ecosystems raises ecological concerns. This study demonstrates that the photodegradation of polylactic acid (PLA), polyhydroxybutyrate (PHB), and cellulose acetate (CA) in artificial seawater substantially increased toxicity under the elevated laboratory conditions used, compared with virgin counterparts, adversely affecting the development and growth of seaweeds. Those aged biopolymers and their leached substances impaired the growth and development of the green macroalgae Ulva (Chlorophyta) under standardized conditions, but the ecological relevance at natural seawater concentrations is likely lower. Chlorophyll a fluorescence, median lethal concentration (LC50-values), and HR-MS analysis corroborated these findings, emphasizing detrimental impacts on the fitness and development of Ulva mutabilis. Toxic effects were linked to substances released during photodegradation and hydrolysis, especially for PLA and PHB. PLA exhibited a 6.7-fold increase in toxicity following UV exposure; LC50-values indicate increased toxicity from direct polymer exposure and from leached compounds at the applied concentration. PHB exhibited the strongest degradation-related toxicity, with over a 10-fold increase. CA was the most toxic overall, with an LC50-value of <0.5 mg/mL in aged samples under laboratory conditions. Even nonaged CA showed effects at these elevated concentrations, but environmental relevance remains uncertain. Although this is an explorative model study in lab scale using elevated concentrations, the observed persistence and (post-)degradation effects of biomicroplastics highlight potential polymer-specific toxicity and emphasize the need for further research on the degradation of biopolymers in the marine environment.
    Universitätsbibliographie Jena:
    fsu_mods_00028707Externer Link

  3. Alternative Gas Diffusion Electrode Designs: Influence of Porosity Gradients on the Electrochemical Activity

    ErscheinungsjahrErschienen in:Advanced Energy and Sustainability Research A. Bekisch, K. Skadell, J. Ast, M. Schulz, R. Weidl, S. Christiansen, M. Stelter
    In this study, it is revealed that carbon-free gas diffusion electrodes (CF-GDEs) with macropore sizes outperform the a carbon-based GDE (GDErₑf). These CF-GDEs exhibit notably reduced overpotentials and increased electrochemical stability. By combining three distinct macropore-sized substrates, coated with MnOₓ and hydrophobized with polytetrafluorethylen, a range of CF-GDEs with distinct porosity gradients is designed. In the results, the pivotal role of substrate layers and their hydrophilic/hydrophobic attributes in steering the formation of the electrolyte thin film are unveiled. Specifically, one CF-GDE shows a reduction by one-third of the ηOER (0.24 V) compared to GDErₑf at 10 mA cm−². Noteworthy, this CF-GDE also displays excellent long-term stability without degradation, which is a common issue with carbon-based GDEs due to carbon corrosion. Impressively, the stability measurement conditions the active catalyst sites of the CF-GDE and leads to the formation of NiOₓ, Ni₆MnO₈, and NiMn layered double hydroxides. This results in a doubling of the current densities.
    Universitätsbibliographie Jena:
    fsu_mods_00023527Externer Link

  4. Transverse thermoelectric devices based on thermoelectric oxide ceramics

    Erscheinungsjahr A. Ibrahim
    Universitätsbibliographie Jena:
    fsu_mods_00028286Externer Link

  5. Elimination von Mikroschadstoffen im Wasser mittels hydrodynamischer Kavitation und nichtthermischem Plasma

    Erscheinungsjahr M. Dommke
    Ziel dieser Arbeit war die Entwicklung eines kombinierten Kavitation/Nichtthermisches-Plasma-Verfahrens (HC/NTP) zur Eliminierung von Mikroschadstoffen im Wasser. Nichtthermisches Plasma (NTP) ist vielseitig einsetzbar, wird jedoch durch begrenzten Massentransport reaktiver Sauerstoffspezies eingeschränkt. Durch die Kopplung mit hydrodynamischer Kavitation konnte diese Limitation überwunden werden. Der Abbau des Modellschadstoffs Benzotriazol diente der Prozessbewertung. Zu Beginn wurde ein System mit atmosphärischem Plasma untersucht, das mit einem minimalen Energieeintrag von etwa 33 kWh/m³ eingesetzt werden konnte. Mit Luft als Ionisationsmedium erwies sich die Methode wegen hoher Nitratbildung als ungeeignet. Im kombinierten HC/NTP-System bestimmten abstromseitiger Absolutdruck, Leitfähigkeit, Temperatur und Düsengeometrie die Effizienz. Eine Mindestleitfähigkeit über 100 µS/cm wurde identifiziert, während ein Temperaturmaximum bei 30 °C die effizientesten Abbaubedingungen darstellte. Die Abbaueffizienz stieg mit der Schadstoffkonzentration, während die Geschwindigkeit abnahm. Das kombinierte Verfahren erreichte eine höhere Geschwindigkeitskonstante (0,63 min⁻¹ gegenüber 0,11 min⁻¹ bei atmosphärischem Plasma), gesteigerten Durchsatz (0,210 m³/h) und einen reduzierten Energieverbrauch (14,1 kWh/m³). Zudem wurde der unerwünschte Stickstoffeintrag durch das geschlossene System vermieden. Das HC/NTP-Konzept stellt damit eine energieeffiziente und skalierbare Alternative zu Einzelverfahren dar. Weitere Forschung sollte sich auf den Einfluss von Matrixkomponenten, die Optimierung des Energieeintrags im Ultraspurenbereich und die Anwendung in Realwassersystemen konzentrieren.
    Universitätsbibliographie Jena:
    fsu_mods_00028997Externer Link

  6. Integrated characterization of hydrodynamic cavitation: optical, chemical, and simulation correlations

    ErscheinungsjahrErschienen in:Chemical engineering science J. Xiao, M. Dommke, M. Franke, M. Stelter, P. Braeutigam
    Hydrodynamic cavitation (HC) is an advanced oxidation process for degrading micropollutants, primarily driven by hydroxyl radicals (OH⋅). This study addresses the research gap by characterizing HC under high upstream pressures (up to 60 bar) and integrating chemical, optical, and simulation approaches for a comprehensive characterization of HC processes. OH radical production was quantified with salicylic acid, and bisphenol A (BPA) degradation experiments validated their role in oxidation reactions. Optical methods captured cavitation jet and luminol chemiluminescent images, while simulations estimated vapor bubble formation and cavitation gas fractions. This research focuses on the high-pressure range of 10 to 60 bar in HC systems, demonstrating a proportional relationship between pressure and both the production rate of OH radical and the rate constants of BPA degradation. At 60 bar, the highest concentration of OH radicals and BPA degradation rate were observed. This research enhances the understanding of HC and its potential for optimized pollution control.
    Universitätsbibliographie Jena:
    fsu_mods_00019628Externer Link

  7. Engineered [FeFe]-hydrogenase mimics featuring heteroaryl linkers: molecular design and photocatalytic hydrogen evolution under visible light

    ErscheinungsjahrErschienen in:Inorganic Chemistry Frontiers: an international journal of inorganic chemistry I. Basma, K. Rediger, C. Kasahara, H. Abul-Futouh, M. Micheel, M. Farh, P. Köhler, G. Mlostoń, M. Wächtler, W. Weigand
    Inspired by the active site of [FeFe]-hydrogenase, we have developed synthetic mimics engineered from the reaction of heteroaryl thioketone derivatives ferrocenyl(5-(4-(diphenylamino)phenyl)thiophen-2-yl)methanethione (PS-Fc-1), ferrocenyl(5′-(4-(diphenylamino)phenyl)-[2,2′-bithiophen]-5-yl)methanethione (PS-Fc-2) and phenyl(5′-(4-(diphenylamino)phenyl)-[2,2′-bithiophen]-5-yl)methanethione (PS-Ph) as pro-ligands with Fe3(CO)12. The resulting complexes contain thiolato ligands, which enable a close linkage between heteroaryl chromophores and the catalytic center, thereby promoting efficient photocatalytic hydrogen evolution under visible light irradiation. These mimics incorporate a push–pull organic chromophore, consisting of triphenylamine and (bi)thiophene groups, designed to facilitate direct photoexcitation into a charge-separated state. Electrochemical properties were examined using cyclic voltammetry, and photophysical characteristics were determined by steady-state spectroscopy and nanosecond transient absorption supported by (TD-)DFT simulations. Whilst both catalytically active species revealed the formation of charge-separated states directly upon excitation, fast deactivation due to relaxation into low-lying ferrocene-located states prevents the formation of long-lived excited states in the ferrocene-linked dyad. This explains the reduced activity for hydrogen generation of the dyad containing the ferrocene moiety compared to the phenyl one.
    Universitätsbibliographie Jena:
    fsu_mods_00028319Externer Link

  8. Seasonal dynamics of micro- and nanoplastics and associated pollutants in Aarin River: Insights into abundance and digestion impact

    ErscheinungsjahrErschienen in:Cleaner Water R. Oladeji, L. Azeez, B. Agbaogun, M. Shakirat, A. Oladejo, H. Aremu, H. Busari, O. Awolola, A. Hammed
    Universitätsbibliographie Jena:
    fsu_mods_00026375Externer Link

  9. Variability in microplastic abundance, bisphenol A contamination, antioxidant properties, and health risks associated with vegetable consumption

    ErscheinungsjahrErschienen in:Beni-Suef University Journal of Basic and Applied Sciences L. Azeez, R. Adetoro, B. Agbaogun, A. Oyedeji, H. Busari, A. Oladejo, O. Oyelami, O. Deborah, R. Oladeji, S. Basiru, S. Muhammad-Lawal, A. Hammed, A. Makanjuola
    Background: Plastic pollution, particularly microplastics (MPs) and toxic additives such as bisphenol A (BPA), endangers human health. Therefore, their routes in the environment need to be investigated. This study investigated microplastic (MPs) abundance, bisphenol A (BPA) levels, and antioxidant activity (AA) in three commonly consumed vegetables—green amaranth, jute mallow, and spinach sourced from two markets in Osogbo, southwestern Nigeria. Microscopic technique was used to determine MP abundance, shapes, and colours. High-performance Liquid Chromatography (HPLC) was used to analyse BPA contents while 2,2-diphenyl-1-picrylhydrazyl (DPPH) assay was used to measure AA. A hazard index (HI) and estimated dietary intakes (EDIs) were used to estimate the associated risks and food safety concerns with MP and BPA in vegetables. Results: In this study, MP abundance in shoots ranged from 4.00 ± 0.50 to 7.67 ± 1.04 particles/g and in roots from 5.33 ± 1.53 to 18.00 ± 6.93 particles/g in spinach and green amaranth, respectively, indicating subsoil contamination. Three shapes (fragment, fibre, and irregular) and five colours (transparent, white, yellow, black, and brown) were detected, with fragment shape and transparent colour dominating. Fourier Transform Infrared spectroscopic (FTIR) analysis revealed a predominance of polyethylene, polypropylene, polyethylene terephthalate, polyvinyl chloride, and polyamide microplastics. The BPA ranged from 5.55 ± 0.56 to 6.65 ± 0.00 μg/g while AA ranged from 40.67 ± 6.79 to 72.55 ± 4.03%. A regression analysis and principal component analysis (PCA) were used to identify the relationship among the factors (MPs, BPA, and AA). It is suggested that high levels of MPs and BPA negatively impacted vegetable quality as they are associated with environmental contamination. Contrastingly, AA had a significant positive correlation with vegetable quality. Both EDIs and HI of MPs and BPA were < 1, indicating no significant risk associated with BPA exposure from their consumption. Conclusion: This study highlights the potential health risks of MPs and associated BPA contamination in vegetables. The estimated dietary intake and hazard index suggest no immediate health risks, but long-term exposure remains a concern. MPs and BPA in commonly consumed vegetables warrant stricter monitoring of agricultural soil and irrigation water sources. Microplastic exposure in food crops can be reduced with policies that regulate plastic waste disposal and promote sustainable farming practices.
    Universitätsbibliographie Jena:
    fsu_mods_00024433Externer Link

  10. Experimental and density function theory-guided mechanistic insights into triclosan removal using a tripartite AgNPs/nanobiochar/Co-MOF composite

    ErscheinungsjahrErschienen in:Cleaner Water Y. Ayinde, L. Azeez, S. Popoola, S. Adebisi, A. Oladejo, S. Basiru, B. Agbaogun, R. Oladeji
    A tripartite composite comprising nanobiochar, nanoparticles (AgNPs), and cobalt-based metal organic frameworks (Co-MOF) - AgNPs/nanobiochar/Co-MOF was synthesized and characterized. The incorporation of AgNPs and nanobiochar onto Co-MOF was confirmed via Fourier transform infrared spectroscopy (FTIR), energydispersive X-ray (EDX) results, and molecular docking optimization. The adsorption mechanism was investigated experimentally and computationally using Density functional theory (DFT). The pH of maximum adsorption and point of zero charge of the AgNPs/nanobiochar/Co-MOF composite was observed at 4 and 8.8, respectively. The composite removal efficiency of triclosan (TRC) decreased with initial concentration and temperature but increased with contact time and adsorbent dose. The adsorption processes were best fitted to the Freundlich isotherm with a maximum monolayer adsorption (qmax) of 117.88 mg g− 1 and appropriately described by pseudo-second order kinetics. Thermodynamic parameters revealed spontaneous and exothermic adsorption with negative enthalpy (-ΔH◦) and decreasing free energy (-ΔG◦) values with an increase in temperature (303–333 K). The DFT-guided molecular docking (DFT) revealed that the adsorption process was exergonic, involving an electron transfer mechanism from triclosan (TRC) to the composite. The interaction in complex [HO—Co and Ph2O—Co] was more energetically favourable than complex [Cl—Co] as reflected by higher binding energy and shorter interatomic distance.
    Universitätsbibliographie Jena:
    fsu_mods_00028643Externer Link

  11. Activity measurements and calculations for gamma-emitting radionuclides in concrete drill cores of unit 2 of the Greifswald NPP

    ErscheinungsjahrErschienen in:ISRD 17 - International Symposium on Reactor Dosimetry (Part II) E. Poenitz, Q. Roode-Gutzmer, A. Barkleit, J. Konheiser
    Due to Germany's nuclear phase-out, decommissioning and final disposal of construction materials of Nuclear Power Plants (NPP) become increasingly important. The reliable determination of radionuclides produced by neutron activation, the activity as a function of time since shutdown and investigation of subsequent radionuclide mobility are subject of a research project. Drill cores of the concrete shielding of unit 2 of the Greifswald NPP were retrieved. Specific activities of gamma emitters and the elemental composition were measured. The radiation transport code MCNP 6 was used for the calculation of spectral neutron fluences. A neutron radiation field calculation reveals that the maximum neutron fluence at the concrete component is located in the floor just below the RPV. The concrete structures closest to the reactor core are shielded efficiently against neutron radiation by the annular water tank. Measured and calculated specific activities of ¹⁵²Eu, ¹⁵⁴Eu and ⁶⁰Co for the cement screed at the position of the maximum neutron fluence are surprisingly low. A specific exemption (i.e. release from radiation protection surveillance but mandatory for final disposal) of the screed sample according to Germany's Radiation Protection Ordnance is expected to be possible approximately 4 decades after the shutdown of the NPP.
    Universitätsbibliographie Jena:
    fsu_mods_00027608Externer Link

  12. Synthesis and characterization of Chabazite membranes for gas seperation applications

    Erscheinungsjahr A. Taherizadeh
    Separating mixtures is crucial in industry but consumes significant energy. Membrane technology offers an energy-efficient alternative. It uses selective membranes to separate specific components from a mixture. Pressure is the most common driving force for this process. Microporous materials like zeolites are particularly useful for molecular separation due to their well-defined pore sizes. These pores act like sieves, allowing only molecules of a certain size to pass through. Chabazite (CHA) zeolites, with pores similar in size to methane (CH4) but larger than carbon dioxide (CO2), are promising for separating these gases. This research focused on developing CHA membranes for CO2/CH4 separation. The researchers synthesized, characterized, and evaluated these membranes. They also investigated factors affecting their performance, like pore size and synthesis conditions. Finally, they tested the membranes' effectiveness in separating CO2 from CH4 mixtures, demonstrating their potential for biogas upgrading. The final membranes achieved a CO2/CH4 selectivity of 122 (single gas) and 173 (mixed gas), with good CO2 permeance. These results suggest their promise for large-scale applications.
    Universitätsbibliographie Jena:
    fsu_mods_00014538Externer Link
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