Validation of biomarker-based dual and coupled stable isotope approaches for reconstructing lake water evaporation in palaeohydrology
- Erscheinungsjahr
- Erschienen in:
- Palaeogeography, palaeoclimatology, palaeoecology
Compound-specific stable hydrogen (δD) and oxygen (δ ¹⁸ O) isotopes of aquatic and terrestrial biomarkers in lake sediments are widely used to reconstruct palaeohydrology, recording variations in precipitation and evaporation. The two main approaches are the dual biomarker approach, based on the isotopic differences between δD of aquatic and terrestrial n-alkanes, and the coupled isotope approach, combining n-alkanes (δD n₋ₐlkₐnₑ ) with hemicellulose-derived sugars (δ ¹⁸ O sugₐr ) to reconstruct deuterium-excess (d-excess). Both are commonly applied in palaeohydrology, but so far, they were never directly compared to each other. We analysed δ ¹⁸ O sugₐr in surface sediments from Lake Khar Nuur, Mongolia, complementing an existing dual biomarker δD n₋ₐlkₐnₑ dataset. The sugar biomarker fucose was identified as an aquatic endmember in the sediments. The δ ¹⁸ O fucₒsₑ is therefore used as a proxy for δ ¹⁸ O lₐkₑ wₐtₑr , which is modulated by evaporative enrichment of lake water like δD n₋C₂₃ . Both isotopes significantly correlate and show high evaporative enrichment in the central basins. By coupling the aquatic endmembers δD n₋C₂₃ and δ ¹⁸ O fucₒsₑ , we calculated aquatic d-excess and precipitation δD and δ ¹⁸ O. Results closely match those from the dual biomarker approach and precisely align with the local isotopic signature of growing season precipitation. Similar results for d-excess and precipitation were obtained using a modified coupled isotope approach based on terrestrial δD n₋C₃₁ and aquatic δ ¹⁸ O fucₒsₑ . Overall, our results depict the sensitivity of biomarker compounds in the lake's sediment accumulation zone for environmental processes. The methodological comparison confirms the compatibility of dual and coupled isotope approaches and supports their application in molecular palaeohydrology.
- Universitätsbibliographie Jena:
- fsu_mods_00036621Externer Link